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The shocking image of North Korean dictator Kim Jong-un's half brother, slumped in a chair moments after being poisoned, has emerged.

Dizzy and in pain, Kim Jong-nam told medics at Kuala Lumpur airport that he had been sprayed with a chemical. He died on his way to hospital on Monday.

Kim, the estranged brother of the secretive state's despot ruler, had once been expected to lead North Korea, but was instead exiled because his family felt he was 'too westernised'.

The finger of blame has been pointed at Pyongyang, with South Korea's spy agency saying Kim Jong-un killed his half brother out of 'paranoia'.

It is unclear why he was killed, amid rumours that he was planning to set up a government in exile.

It is reported that a police statement says the man identified as Ri Jong Chol was arrested on Friday in Selangor near Kuala Lumpur

Pictured is the CCTV image released by Police in the search for three more men over the murder

Suspect Siti Aisyah was reportedly approached by North Korean agents in a nightclub, where she was led to believe she would be carrying out a prank

The latest suspect to be arrested was carrying a North Korean passport identifying him as a 46-year-old man named Ri Jong Chol.

It is reported that Investigators believe North Korean agents behind the killing were watching from an airport restaurant, 50 metres from where Kim was poisoned.

Police believe a woman wearing a top with 'LOL' inscribed on it approached the victim from behind and thrust a deadly poisonous substance into his face.

Reportedly Yesterday Indonesia's police chief said one of the suspects, Indonesian Siti Aishah, was duped into thinking she was part of a comedy show prank.

It has been claimed that she was approached in a nightclub and offered $100 to carry out the act. She did not know who Kim was, it is believed.

The woman claims she and Vietnamese accomplice Doan Thi Huong, 29 - who was wearing the ‘LOL’ T-shirt - were duped into carrying out the assassination by North Korean agents

31-year-old, Dictator Kim Jong-Un

It is reported that Malaysian police have announced the arrest of a fourth suspect, a North Korean, in the death of Kim Jong-nam, left, the half brother of dictator Kim Jong-un, right

Photo credit- Daily Mail UK